UN/NA Number Reference
DOT Class 3 Flammable Liquid placard

UN 2554: Methylallyl chloride

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 2554 is assigned the proper shipping name Methylallyl chloride in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 3 Flammable Liquid material, Packing Group II. Required label(s): 3.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 130)

Hazards: Flammable. Toxic vapor. Harmful if inhaled or absorbed. May accumulate in low areas.

Fire: Dry chemical, CO2, foam, water spray. Do not use straight streams.

Spill: Eliminate ignition sources. Stop leak. Absorb with sand/earth. Prevent waterway contamination.

Chemical and Physical Properties

Methylallyl chloride appears as a colorless to straw-colored liquid with a sharp penetrating odor. Less dense than water and insoluble in water. Flash point below 0 °F. May be toxic by ingestion. Irritating to skin and eyes. Used to make plastics and pharmaceuticals.

CAS Number: 563-47-3
Molecular Formula: C4H7Cl
Molecular Weight: 90.55 g/mol
Color / Form: COLORLESS TO STRAW-COLORED LIQUID
Odor: SHARP, PENETRATING
Boiling Point: 160 to 162 F
Melting Point: less than -112 °F (NTP, 1992)
Flash Point: 9 F
Autoignition: 540 °C
Specific Gravity: 0.928 (floats on water)
Vapor Pressure: 101.7 mmHg at 68 F
Vapor Density: 3.12 (heavier than air)
Water Solubility: less than 1 mg/mL at 70 F
Log P: 1.98

Special Provisions

49 CFR 172.102 special provision codes for this entry: IB2, T4, TP1, TP13. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 2554 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.