UN/NA Number Reference
DOT Class 2.3 Toxic Gas placard

UN 2202: Hydrogen selenide, anhydrous

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 2202 is assigned the proper shipping name Hydrogen selenide, anhydrous in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 2.3 Toxic Gas material. Required label(s): 2.3, 2.1.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 119)

Hazards: TOXIC. May be fatal if inhaled or absorbed through skin. Flammable. Vapors heavier than air.

Fire: Small: dry chemical or CO2. Large: water spray or fog. Fight from maximum distance.

Spill: Do not touch. Stop leak if safe. Use water spray to reduce vapor.

Chemical and Physical Properties

Hydrogen selenide is a colorless gas with an offensive odor. It is highly flammable and toxic. It may be irritating to eyes and mucous membranes. It is heavier than air. Long term exposure to low concentrations or short term exposure to high concentrations can result in adverse health effects from inhalation. If exposed to prolonged fire or intense heat the containers may violently rupture or rocket. Rate of onset: Immediate Persistence: Minutes - hours Odor threshold: 0.3 ppm Source/use/other hazard: Metals &semiconductor preparation; highly flammable/explosive; can cause burns/frostbite; decomposes rapidly to form elemental selenium

CAS Number: 7783-07-5
Molecular Formula: H2Se
Molecular Weight: 80.99 g/mol
Color / Form: Colorless gas
Odor: Odor resembling decayed horseradish
Boiling Point: -42.3 F
Melting Point: -86.31 °F (EPA, 1998)
Flash Point: Flammable gas
Specific Gravity: 2.12 at -42 C/4 C (liquid)
Vapor Pressure: 6536 to 9120 mmHg at 64.4 to 87.44 F
Vapor Density: 2.12 at -43.6 F
Water Solubility: 0.9 % at 73 F
pH: Aqueous solution is weakly acidic, although it is stronger than aqueous acetic acid

Regulatory Data

CERCLA RQ (40 CFR 302.4)
1 lb
EPCRA TPQ (40 CFR 355)
10 lb
OSHA PEL
TWA 0.05 ppm (0.2 mg/m 3 )
NIOSH REL
TWA 0.05 ppm (0.2 mg/m 3 )
IDLH
1 ppm

A release of this material at or above its CERCLA reportable quantity (1 lb) requires immediate notification to the National Response Center at 800-424-8802.

Special Provisions

49 CFR 172.102 special provision codes for this entry: 1. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 2202 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.