UN/NA Number Reference
DOT Class 2.2 Non-Flammable Gas placard

UN 1958: 1,2-Dichloro-1,1,2,2-tetrafluoroethane

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 1958 is assigned the proper shipping name 1,2-Dichloro-1,1,2,2-tetrafluoroethane in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 2.2 Non-Flammable Gas material. Required label(s): 2.2.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 126)

Hazards: May cause asphyxiation. May cause frostbite. Containers may rocket.

Fire: Let fire burn unless leak can be stopped. Cool surrounding containers with water.

Spill: Stop leak if safe. Ventilate area. Prevent gas from entering low areas.

Chemical and Physical Properties

1,2-Dichloro-1,1,2,2-tetrafluoroethane is a colorless, nearly odorless nonflammable gas. It may be mildly toxic and irritating by inhalation. It can asphyxiate by the displacement of air. Exposure of the container to prolonged heat or fire can cause it to rupture violently and rocket. It is used as a solvent and as a fire extinguishing agent.

CAS Number: 76-14-2
Molecular Formula: C2Cl2F4
Molecular Weight: 170.92 g/mol
Color / Form: Colorless gas ... [Note: A liquid below 38 degrees F. Shipped as a liquefied compressed gas]
Odor: Faint, ether-like odor at high concentrations
Boiling Point: 38.8 F
Melting Point: -137 °F (USCG, 1999)
Specific Gravity: 1.455 g/cu cm
Vapor Pressure: 2616.02 mmHg
Vapor Density: 1.455 (heavier than air)
Water Solubility: 0.01 %
Log P: log Kow = 2.82

Regulatory Data

CERCLA RQ (40 CFR 302.4)
1 lb
OSHA PEL
TWA 1000 ppm (7000 mg/m 3 )
NIOSH REL
TWA 1000 ppm (7000 mg/m 3 )
IDLH
15,000 ppm

A release of this material at or above its CERCLA reportable quantity (1 lb) requires immediate notification to the National Response Center at 800-424-8802.

Special Provisions

49 CFR 172.102 special provision codes for this entry: T50. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 1958 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.