UN/NA Number Reference
DOT Class 3 Flammable Liquid placard

UN 1919: Methyl acrylate, stabilized

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 1919 is assigned the proper shipping name Methyl acrylate, stabilized in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 3 Flammable Liquid material, Packing Group II. Required label(s): 3.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 129)

Hazards: Flammable. Irritating vapor. May cause dizziness. Toxic if inhaled or absorbed through skin.

Fire: Alcohol-resistant foam, dry chemical, CO2, water spray.

Spill: Eliminate ignition sources. Ventilate area. Absorb with earth or sand.

Chemical and Physical Properties

Methyl acrylate, stabilized is a colorless volatile liquid with an acrid odor. Flash point 27 °F. Vapors may irritate the eyes and respiratory system. Highly toxic by inhalation, ingestion and skin absorption. Less dense than water (0.957 gm / cm3) and slightly soluble in water, hence floats on water. Vapors heavier than air.

CAS Number: 96-33-3
Molecular Formula: C4H6O2
Molecular Weight: 86.09 g/mol
Color / Form: Colorless volatile liquid
Odor: Acrid odor
Boiling Point: 177 F
Melting Point: -105.7 °F (NTP, 1992)
Flash Point: 44 F
Autoignition: 875 °F (NTP, 1992)
Specific Gravity: 0.956
Vapor Pressure: 40 mmHg
Vapor Density: 3 (heavier than air)
Water Solubility: 10 to 50 mg/mL at 72 °F (NTP, 1992)
Log P: log Kow = 0.80

Regulatory Data

CERCLA RQ (40 CFR 302.4)
1 lb
OSHA PEL
TWA 10 ppm (35 mg/m 3 ) [skin]
NIOSH REL
TWA 10 ppm (35 mg/m 3 ) [skin]
IDLH
250 ppm

A release of this material at or above its CERCLA reportable quantity (1 lb) requires immediate notification to the National Response Center at 800-424-8802.

Special Provisions

49 CFR 172.102 special provision codes for this entry: 387, IB2, T4, TP1, TP13. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 1919 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.