UN/NA Number Reference
DOT Class 6.1 Toxic Substance placard

UN 1738: Benzyl chloride

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 1738 is assigned the proper shipping name Benzyl chloride in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 6.1 Toxic Substance material, Packing Group II. Required label(s): 6.1, 8.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 156)

Hazards: TOXIC or CORROSIVE. FLAMMABLE. Vapors may travel to ignition source.

Fire: Alcohol-resistant foam, dry chemical, CO2. Water spray for cooling only.

Spill: Eliminate ignition sources. Do not touch. Ventilate area.

Chemical and Physical Properties

Benzyl chloride appears as a colorless liquid with an irritating odor. Toxic by inhalation and skin absorption. Flash point 153 °F. Slightly soluble in water. Corrosive to metals and tissue. A lachrymator. Density 9.2 lb /gal.

CAS Number: 100-44-7
Molecular Formula: C7H7Cl
Molecular Weight: 126.58 g/mol
Color / Form: Colorless to slightly yellow liquid
Odor: Rather unpleasant, irritating odor
Boiling Point: 354 F
Melting Point: -54 to -45 °F (EPA, 1998)
Flash Point: 153 F
Autoignition: 1161 °F (USCG, 1999)
Specific Gravity: 1.1 (sinks in water)
Vapor Pressure: 1 mmHg at 71.6 F
Vapor Density: 4.4 (heavier than air)
Water Solubility: Reaction
Log P: log Kow = 2.30

Regulatory Data

CERCLA RQ (40 CFR 302.4)
100 lb
EPCRA TPQ (40 CFR 355)
500 lb
OSHA PEL
TWA 1 ppm (5 mg/m 3 )
NIOSH REL
C 1 ppm (5 mg/m 3 ) [15-minute]
IDLH
10 ppm
RCRA Waste Code(s)
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A release of this material at or above its CERCLA reportable quantity (100 lb) requires immediate notification to the National Response Center at 800-424-8802.

Special Provisions

49 CFR 172.102 special provision codes for this entry: A3, A7, B8, B11, IB2, N33, N34, N43, T8, TP2, TP13. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 1738 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.