UN/NA Number Reference
DOT Class 2.1 Flammable Gas placard

UN 1077: Propylene

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 1077 is assigned the proper shipping name Propylene in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 2.1 Flammable Gas material. Required label(s): 2.1.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 115)

Hazards: Extremely flammable. May be ignited by heat, sparks, or flames. Vapors may travel to ignition source and flash back. Containers may rocket or BLEVE.

Fire: Do not extinguish unless flow can be stopped. Use water spray to cool containers. Move containers from fire if safe.

Spill: Eliminate ignition sources. Stop leak if safe. Use water spray to reduce vapors.

Chemical and Physical Properties

Propylene is a colorless gas with a faint petroleum like odor. It is shipped as a liquefied gas under its own vapor pressure. For transportation it may be stenched. Contact with the liquid can cause frostbite. It is easily ignited. The vapors are heavier than air. Any leak can either be liquid or vapor. It can asphyxiate by the displacement of air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. It is used to make other chemicals. Can cause explosion.

CAS Number: 115-07-1
Molecular Formula: C3H6
Molecular Weight: 42.08 g/mol
Color / Form: Colorless gas
Odor: Practically odorless; aromatic
Boiling Point: -53.9 F
Melting Point: -301.4 °F (NTP, 1992)
Flash Point: -162 °F (NTP, 1992)
Autoignition: 851 °F (USCG, 1999)
Specific Gravity: 0.609 at -52.6 F
Vapor Pressure: 1 mmHg at -205.4 F
Vapor Density: 1.46 (heavier than air)
Water Solubility: 44.6 mL/100 mL
Log P: log Kow = 1.77

Regulatory Data

CERCLA RQ (40 CFR 302.4)
1 lb

A release of this material at or above its CERCLA reportable quantity (1 lb) requires immediate notification to the National Response Center at 800-424-8802.

Special Provisions

49 CFR 172.102 special provision codes for this entry: 19, T50. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 1077 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.