UN/NA Number Reference
DOT Class 4.1 Flammable Solid placard

UN 3241: 2-Bromo-2-nitropropane-1,3-diol

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 3241 is assigned the proper shipping name 2-Bromo-2-nitropropane-1,3-diol in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 4.1 Flammable Solid material, Packing Group III. Required label(s): 4.1.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 133)

Hazards: Flammable. May be ignited by friction, heat, sparks. May burn rapidly with flare-burning effect.

Fire: Water spray, foam, dry chemical. Some may be extinguished with CO2.

Spill: Eliminate ignition sources. Do not touch. Cover with dry earth, sand, or non-combustible material.

Chemical and Physical Properties

2-bromo-2-nitropropane-1,3-diol appears as white crystals. Ignite easily and burn readily. May detonate under strong shock. Decomposes when heated, evolving toxic gases. Toxic by skin absorption, inhalation or ingestion.

CAS Number: 52-51-7
Molecular Formula: C3H6BrNO4
Molecular Weight: 199.99 g/mol
Color / Form: White crystalline powder
Odor: Odorless
Boiling Point: 305.1 F
Melting Point: 266 to 271 °F (NTP, 1992)
Flash Point: 167Â °C
Specific Gravity: Relative density (water = 1): 1.9
Vapor Pressure: 1.2601e-05 mmHg at 68 F
Water Solubility: greater than or equal to 100 mg/mL at 63 F
Log P: -0.6

Special Provisions

49 CFR 172.102 special provision codes for this entry: 46, IB8, IP3. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 3241 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.