UN/NA Number Reference
DOT Class 2.1 Flammable Gas placard

UN 2200: Propadiene, stabilized

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 2200 is assigned the proper shipping name Propadiene, stabilized in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 2.1 Flammable Gas material. Required label(s): 2.1.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 116)

Hazards: May polymerize explosively when heated or involved in fire. Extremely flammable. BLEVE risk.

Fire: Fight fire from maximum distance. Do not extinguish unless flow stopped. Cool containers with water.

Spill: Eliminate all ignition sources. Stop leak if safe.

Chemical and Physical Properties

Propadiene, stabilized appears as a colorless flammable gas. May become unstable. Not toxic but asphyxiation may occur because of displacement of oxygen. Under prolonged exposure to fire or heat the containers may rupture violently and rocket.

CAS Number: 463-49-0
Molecular Formula: C3H4
Molecular Weight: 40.06 g/mol
Color / Form: GAS
Boiling Point: -30 F
Melting Point: -136 °C
Specific Gravity: 1.787
Vapor Pressure: 5430.0 mmHg
Water Solubility: Insoluble in water

Special Provisions

49 CFR 172.102 special provision codes for this entry: 387. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 2200 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.