UN/NA Number Reference
DOT Class 5.1 Oxidizer placard

UN 1445: Barium chlorate, solid

49 CFR 172.101 Hazardous Materials Table·ERG 2024

DOT Classification and Shipping

UN 1445 is assigned the proper shipping name Barium chlorate, solid in the U.S. DOT Hazardous Materials Table (49 CFR 172.101). It is classified as a Class 5.1 Oxidizer material, Packing Group II. Required label(s): 5.1, 6.1.

Packing group indicates the degree of danger within a hazard class: PG I is high danger, PG II medium, PG III low. The proper shipping name, hazard class, UN number, and packing group together form the basic shipping description that must appear on shipping papers and, where required, on the package and placard.

Emergency Response (ERG Guide 141)

Hazards: Oxidizer. TOXIC. May be fatal if inhaled or swallowed. Accelerates combustion.

Fire: Use flooding water. Do not use dry chemical, foam.

Spill: Do not touch. Keep combustibles away. Use water spray.

Chemical and Physical Properties

Barium chlorate appears as a white crystalline solid. Forms very flammable mixtures with combustible materials. Mixtures may be ignited by friction and may be explosive if the combustible material is finely divided. Contact with concentrated sulfuric acid solutions may cause fires or explosions. May spontaneously decompose and ignite when mixed with ammonium salt. May explode under prolonged exposure to heat or fire. Used in explosives and pyrotechnics, in dyeing textiles, and to make other chlorates.

CAS Number: 13477-00-4
Molecular Formula: BaCl2O6
Molecular Weight: 304.23 g/mol
Color / Form: White crystals
Melting Point: 777 °F (USCG, 1999)
Specific Gravity: 3.18
Water Solubility: White odorless solid; solubility: 20.350 lb/100 lb water at 32 °F; heat of so...

Special Provisions

49 CFR 172.102 special provision codes for this entry: A9, IB6, IP2, N34, T3, TP33. These codes modify the general requirements (packaging, quantity limits, exceptions) for this specific material. Look up each code in 49 CFR 172.102 for the full text.

Need the full interactive record? Open UN 1445 in the SpillNerd lookup tool for the live database entry with placard graphics, GHS pictograms, full segregation tables, and synonym search. For another material, use the UN number and chemical lookup.

Reference data compiled from the DOT Hazardous Materials Table (49 CFR 172.101), the 2024 Emergency Response Guidebook, and public chemical databases (PubChem, NIOSH, EPA). Always verify the correct shipping description against the current regulation and the manufacturer's SDS Section 14 before shipping.